- Selectivity in radical reactions of alanylglycine anhydride derivatives
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Functionalization of N,N′-disubstituted alanylglycine anhydrides under radical conditions is described. The radical (7), generated (i) from reactions of N,N′-disubstituted alanylglycine anhydrides with N-bromosuccinimide, and (ii) from related bromo compounds by reaction with tributyltin deuteride, undergoes carbon-bromine and carbon-deuterium bond formation with moderate to high diastereoselectivities depending on the N-substituents present.
- Chai, Christina L.L.,Hay, Darren B.,King, Alison R.
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p. 605 - 610
(2007/10/03)
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