Ruthenium(II) and ruthenium(III) complexes have been found to be the first efficient catalysts for the metathesis of organosilicon olefins. trans-1,2-Bis(triethoxysilyl)ethene is prepared via metathesis of vinyltriethoxysilane catalyzed by ruthenium complexes with a yield above 80percent.
Marciniec, Bogdan,Gulinski, Jacek
p. C19 - C21
(2007/10/02)
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