- Silica Anchored Bis(trialkylphosphine) Platinum Oxalate. A Photogenerated Catalyst for Olefin Hydrosilation
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Ultraviolet irradiation of the silica attached complex Pt(C2O4)L2, , yields a -L2Pt species that catalyzes olefin hydrosilation or adds 2 CO to yield a surface dicarbonyl complex. - Keywords: Catalysis; Photochemistry; Supported platinum complex
- Prignano, Andrea L.,Trogler, William C.
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Read Online
- PROCESS FOR THE STEPWISE SYNTHESIS OF SILAHYDROCARBONS
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The invention relates to a process for the stepwise synthesis of silahydrocarbons bearing up to four different organyl substituents at the silicon atom, wherein the process includes at least one step a) of producing a bifunctional hydridochlorosilane by a redistribution reaction, selective chlorination of hydridosilanes with an ether/HCI reagent, or by selective chlorination of hydridosilanes with SiCI4, at least one step b) of submitting a bifunctional hydridochloromonosilane to a hydrosilylation reaction, at least one step c) of hydrogenation of a chloromonosilane, and a step d) in which a silahydrocarbon compound is obtained in a hydrosilylation reaction.
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Page/Page column 65; 67
(2021/12/08)
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- Preparation of polycarboxylic acid-functionalized silica supported Pt catalysts and their applications in alkene hydrosilylation
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A series of novel immobilized platinum catalysts was prepared by loading Pt onto silica particles modified with polycarboxylic acid groups such as diethylenetriaminepentaacetic acid (DTPA), nitrolotriacetic acid (NTA) and succinic acid (SA). The three modified heterogeneous Pt catalysts were characterized using infrared spectroscopy (IR), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), energy dispersive X-ray spectroscopy (EDS) and atomic absorption spectroscopy (AAS). The residual H2PtCl6 solutions were characterized using ultraviolet spectroscopy (UV). The polycarboxylic acid-functionalized silica supported Pt catalysts were used to catalyze alkene hydrosilylation and 1-hexene was chosen as a model alkene. The data indicated that the catalytic performance was strongly dependent on the properties of the polycarboxylic acid group bonded to the silica particles. Among them, DTPA-functionalized silica supported Pt (SiO2-DTPA-Pt) showed the best catalytic activity and reusability. Furthermore, some hydrosilylation reactions between other linear alkenes (1-heptene, 1-octene, 1-decene, 1-do-decene, 1-tetra-decene, 1-hexa-decene, 1-octa-decene, styrene or cis-hex-2-ene), or ring type alkenes (norbornene) with methyldichlorosilane could be catalyzed in the presence of these three Pt catalysts. Their high activities were more than 90%, and their selectivities were more than 99%, which were apparently better than homogeneous Pt catalysts. In addition, reactions with cyclohexene were also successfully catalyzed by the Pt catalysts. These results indicate that the polycarboxylic acid-functionalized silica gel supported Pt catalysts have potential value in industrial hydrosilylation reactions.
- Shao, Dongyun,Li, Youxin
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p. 20379 - 20393
(2018/06/11)
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- Effect of catalysts on the reaction of allyl esters with hydrosilanes
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The reaction of hydrosilylation of allyl esters XOCH 2CH=CH 2 (X = MeCO, CF 3CO, C 3F 7CO) and PhOCH 2CH=CH 2 with hydrosilanes HSiY 3 (Y = Cl, OEt) in the presence of the Speier catalyst, the Speier catalyst with additives, and of various nickel complexes was studied. The catalytic hydrosilylation reaction in the presence of the Speier catalyst is accompanied by the reduction. Additives to the Speier catalyst (vinyltriethoxysilane and some ethers) allow to suppress considerably the reduction reaction. In the presence of the studied nickel complexes mainly reduction and isomerization reactions occurred. The best nickel catalysts of hydrosilylation were the mixtures of NiCl 2 or Ni(acac) 2 with phosphine oxides. In contrast to allyl esters, the hydrosilylation of simple olefins proceeds easier, the content of the product of hydrosilylation in the reaction mixture reaches 94.3%. Pleiades Publishing, Ltd., 2010.
- Belyakova,Pomerantseva,Efimova,Chernyshev,Storozhenko
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experimental part
p. 728 - 733
(2011/01/05)
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- INFLUENCE OF LIGANDS IN THE COMPLEXES Pt(Ph3E)2X2 (E = P, As, Sb; X = Cl, I, NO2, SCN, 1/2SO3) ON THEIR CATALYTIC PROPERTIES IN HYDROSILYLATION REACTIONS
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The catalytic activity of the complexes cis-Pt(Ph3E)2X2 in the hydrosilylation of 1-heptene with methyldichlorosilane was assessed quantitatively.The considerable increase in the activity of complexes in the series of Group V elements P Cl > I > SCN.
- Titov, K. E.,Gavrilenko, F. A.,Vorob'ev-Desyatovskii, N. V.,Skvortsov, N. K.
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p. 1600 - 1603
(2007/10/02)
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