A Kinetic Study of the Hydrolysis of Aryl Esters by the pH-Stat Method
The rates of hydrolysis of a series of aryl acrylates and aryl acetates in water at 24 deg C have been monitored by the pH stat method.The second-order rate coefficients for base-induced reactions (kOH) determined by this method are consistent with literature values determined under buffered conditions and conform to the conventional BAC2 mechanism for ester hydrolysis.
Marsh, Mary Rose,Gold, Victor,Hall, C. Dennis,Sghibartz, Christopher
p. 1801 - 1814
(2007/10/02)
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