Synthesis of 2-aminooxazolines from isonitriles and iodine
A novel one-pot protocol for the synthesis of substituted 2-aminooxazoline from isonitriles and 2-aminoethanol was developed and the reactions involved imidoyl diiodide intermediates, which were generated by mixing isonitriles and iodine in CH2
Yu, Hui,Li, Yu Zhe,Liu, Qiong,Zhang, Mei Shu,Sun, Wen Liang
experimental part
p. 130 - 132
(2012/06/18)
Investigation of the Mitsunobu reaction of N-(2-hydroxyethyl)-N'- phenyl-ureas
The Mitsunobu reaction of N-(2-hydroxyethyl)-ureas 1 using PPh3 and EtO2CN=NCO2Et led to the mixture of N- and O-alkylation products or a single isomer depending on the substrates.
Kim, Taek Hyeon,Lee, Gue-Jae,Cha, Mi-Hyun
p. 2753 - 2758
(2007/10/03)
Efficient Cyclodesulfurization of N-(2-Hydroxyethyl)-N′-Arylthioureas to Δ2-Oxazolines Using Superoxide Radical Anion
Δ2-Oxazolines have been synthesized in good yields by the cyclodesulfurization of N-(2-hydroxyethyl)-N′-phenylthioureas with superoxide radical anion (O2-?) at room temperature in anhydrous acetonitrile.
Kim, Yong Il,Kim, Yong Hae
p. 1324 - 1326
(2007/10/03)
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