A CHEMOSELECTIVE DESULFURIZATION METHOD VIA HOMOGENEOUS NICKEL CATALYSIS
Isopropylmagnesium bromide in the presence of bis-(triphenylphosphino)-nickel(II) chloride reduces vinyl sulfides stereospecifically to the corresponding olefins without overreduction - a process which serves as a key step in the synthesis of the sex pheromone of the Douglas fir tussock moth.
Trost, Barry M.,Ornstein, Paul L.
p. 3463 - 3466
(2007/10/02)
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