- Photophysical properties and optical power limiting ability of Pt(II) polyynes bearing fluorene-type ligands with ethynyl units at different positions
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Two series of Pt(II) polyynes bearing fluorene-type ligands with ethynyl units at different positions have been synthesized. In the absorption spectra, the Pt(II) polyynes bearing fluorene-type ligands with ethynyl units at 3,6-position have blue-shift with respect to the corresponding analogs bearing fluorene-type ligands with ethynyl units at 2,7-position, showing better transparency in the visible light region. Moreover, the Pt(II) polyynes bearing fluorene-type ligands with ethynyl units at 3,6-position show stronger triplet emission than corresponding analogs bearing fluorene-type ligands with ethynyl units at 2,7-position in the photoluminescent (PL) spectra. Furthermore, these Pt(II) polyynes were applied to optical power limiting (OPL) field. The Pt(II) polyynes bearing fluorene-type ligands with ethynyl units at 2,7-position show better OPL performance than the corresponding analogs with fluorene-type ligands of ethynyl units at 3,6-position. Therefore, changing the position of the ethynyl units in fluorene-type ligands can not only effectively control the photophysical properties of the Pt(II) polyynes, but also has an important effect on their OPL ability.
- Tian, Zhuanzhuan,Yang, Xiaolong,Liu, Boao,Zhong, Daokun,Zhou, Guijiang
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supporting information
p. 28 - 36
(2019/06/05)
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- Benzfluorene derivative and organic light-emitting device containing same
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The invention provides a benzfluorene derivative and an organic light-emitting device containing the same, and relates to the technical field of organic optoelectronic materials. According to the benzfluorene derivative and the organic light-emitting device containing the same, by connecting a substituted or unsubstituted aromatic-ring condensed imidazole derivative and aromatic-ring condensed oxazole derivative onto a benzfluorene main body, the benzfluorene derivative is obtained. The benzfluorene derivative has certain electron transportation capability, is beneficial to compounding of holes and electrons in a light-emitting layer and has good stability and high light-emitting efficiency, synthesis is simple and easy to operate, and the benzfluorene derivative can be applied to the organic light-emitting device as a light-emitting layer doped material, so that the problems can be effectively solved that in the organic light-emitting device, a blue light-emitting material is low in light-emitting efficiency and short in service life, and the organic light-emitting device containing the same has the advantages of being high in light-emitting efficiency and long in service life.
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Paragraph 0086; 0089
(2018/11/22)
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- Fluorene derivative and organic light-emitting device prepared by same
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The invention provides a fluorene derivative and an organic light-emitting device prepared by the same and relates to the technical field of organic photoelectric materials. The fluorene derivative and the organic light-emitting device prepared by the same have the advantages that the fluorene derivative is prepared by connecting substituted or unsubstituted condensed imidazole and condensed oxazole derivatives to a fluorene host, the prepared fluorene derivative has certain electron transport ability, the composition of holes and electrons on a light-emitting layer is benefited, and the fluorene derivative is good in stability and luminous efficiency, simple to synthesize, easy in synthesizing operation, capable of being used in the organic light-emitting device to serve as the light-emitting layer doping material and capable of effectively solving the problems that the blue light-emitting material in the organic light-emitting device is low in luminous efficiency and short in servicelife; the organic light-emitting device is high in luminous efficiency and long in service life.
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Paragraph 0080-0082
(2018/10/19)
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- Bigger and Brighter Fluorenes: Facile π-Expansion, Brilliant Emission and Sensing of Nitroaromatics
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π-Expanded butterfly-like 2D fluorenes and 3D spirobifluorenes 1–5 were synthesized via a DDQ-mediated oxidative cyclization strategy with a high regioselectivity. Through structural modification via π-expansion, it was possible to achieve near-ultraviolet absorption, bright-blue emission, very high near-unity fluorescence quantum yields in solution as well as in film states, and deep-lying HOMO energy levels with excellent thermal stabilities. Furthermore, these electron-rich compounds displayed a notable behavior towards sensing of nitroaromatic explosives, such as picric acid, up to a detection limit of 0.2 ppb.
- Ramakrishna, Jagarapu,Venkatakrishnan, Parthasarathy
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supporting information
p. 181 - 189
(2017/02/05)
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- Photochemical Degradation of Various Bridge-Substituted Fluorene-Based Materials
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Photochemical degradation is an important issue to be overcome in advancing the lifetime of fluorene-containing conjugated polymers. In order to optimize the inertness of the materials, a quantitative measure for the efficiency of degradation is needed. Here, we introduce a method to measure a relative quantum yield of the photochemical degradation by monitoring the kinetics of the process by means of UV/vis spectroscopy and liquid chromatography (LC) techniques. This method is employed to a set of differently substituted 2,7-diphenylfluorenes, serving as model compounds for polyfluorene materials. Our measurements show that the quantum yield changes by orders of magnitude upon varying the bridge substituents and that altered kinetics indicate changing degradation mechanisms.
- Kobin, Bj?rn,Behren, Sandra,Braun-Cula, Beatrice,Hecht, Stefan
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p. 5474 - 5480
(2016/07/30)
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- Binaphthalene derivatives, preparation method thereof and organic electronic device using the same
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The present invention relates to a new binaphthalene derivative, a preparation method thereof, and an organic electronic device using the same. The binaphthalene derivative according to the present invention can perform functions of hole injection and transportation, electron injection and transportation, or light emission in an organic electronic device including an organic light-emitting device, and the device according to the present invention has excellent characteristics in terms of efficiency, drive voltage and stability, and in particular excellent effects such as a low voltage and a long life time.
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Page/Page column 140
(2014/03/26)
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- Novel tri-carbazole modified fluorene host material for highly efficient solution-processed blue and green electrophosphorescent devices
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A series of novel solution-processable small-molecule host materials: 2DPF-TCz, 2SBF-TCz, 27DPF-TCz, and 27SBF-TCz comprising a fluorene monomer as the rigid core and tri-carbazole as the periphery have been designed and synthesized, and their optical, electrochemical, and thermal properties have been fully characterized. The host materials exhibit high glass-transition temperatures (231-310 °C) and high triplet energy levels (2.61-2.73 eV). High-quality amorphous thin films can be obtained by spin-coating the host materials from solutions. It is found that the HOMO level of the host materials can be tuned by linking the tri-carbazole unit to the 2,7 positions of the fluorine core, resulting in appropriate HOMO energy levels (-5.36 to -5.23 eV) for improved hole-injection in the device. Solution-processed blue and green electrophosphorescent devices bases on the developed host materials exhibit high efficiencies of 21.2 and 34.8 cd A-1, respectively.
- Tang, Jinan,Chen, Yuanshen,Cong, Lei,Lin, Baoping,Sun, Yueming
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p. 3847 - 3853
(2014/06/09)
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- LUMINESCENT COMPOUNDS AND ELECTROLUMINESCENT DEVICE USING THE SAME
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The present invention relates to organic electroluminescent compounds and organic electroluminescent devices employing the same. More specifically, the invention relates to organic electroluminescent compounds containing an anthracenyl group or an aryl group having an anthracenyl substituent m the aryl ring of fluorene or indenofluorene, as a blue electroluminescent material in an organic electroluminescent layer. The electroluminescent compounds according to the invention exhibit high luminous efficiency and excellent life property, so that an OLED device having very good operation lifetime can be prepared therefrom.
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Page/Page column 38
(2011/04/14)
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- Sterically encumbered fluorene-based poly(arylene ether)s containing spiro-annulated substituents on the main chain
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Two novel fluorene-based bisphenol monomers containing spiro-annulated substituents on the middle biphenylene moiety have been synthesized in this study. Through reacting with four 2-trifluoromethyl-activated bisfluoro monomers, two monomers were converted into a series of fluorene-based poly(arylene ether)s by nucleophilic displacement of the fluorine atoms on the terminal benzene ring of bisfluoro monomers. The obtained polymers exhibit weight-average molecular weight up to 2.41 × 105 g/mol in GPC. Thermal analysis studies indicated that these polymers did not show melting endotherms but did show ultrahigh Tg values up to 356 °C in DSC and outstanding thermal stability up to 643 °C for 5% weight loss in TGA under nitrogen atmosphere. The polymers are soluble in a wide range of organic solvents, THF, CHCl3, NMP, DMAc, DMF, toluene, etc., and are insoluble in DMSO and acetone at room temperature. Transparent and flexible films were easily prepared by solution casting from chloroform solution of each of the polymers.
- Huang, Wen Y.,Huang
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scheme or table
p. 10355 - 10365
(2011/09/13)
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- NEW BINAPHTHALENE DERIVATIVES, PREPARATION METHOD THEREOF AND ORGANIC ELECTRONIC DEVICE USING THE SAME
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The present invention relates to a new binaphthalene derivative, a preparation method thereof, and an organic electronic device using the same. The binaphthalene derivative according to the present invention can perform functions of hole injection and transportation, electron injection and transportation, or light emission in an organic electronic device including an organic light- emitting device, and the device according to the present invention has excellent characteristics in terms of efficiency, drive voltage and stability, and in particular excellent effects such as a low voltage and a long life time.
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Page/Page column 31-32
(2010/11/27)
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- Ter(9,9-diarylfluorene)s: Highly efficient blue emitter with promising electrochemical and thermal stability
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Novel ter(9,9-diarylfluorene)s were synthesized by a Suzuki-coupling reaction of 2-bromofluorene (1) and 2,7-fluorenediboronic ester derivatives (3) with high isolated yields (63-86%). The X-ray structure analysis of ter(9,9′-spirobifluorene) (4aa) revealed that the conjugated chromophore adopts a helical conformation. This conformation effectively releases the steric interaction between the fluorene moieties and prevents inter-chromophore interactions. The introduction of aryl groups at the C9 position of fluorene was highly beneficial to the thermal and morphological stability of these oligomers. These terfluorenes exhibit intense blue fluorescence with excellent quantum yields both in solution (~100%) and in solid state (66-90%), and possess interesting reversible redox properties. Highly efficient blue light-emitting OLED devices were fabricated using 4aa and 4cc as emitters as well as hole transporters. The devices exhibit low turn-on voltage (~3 V) and high EL external quantum efficiency (2.5-3%). Copyright
- Wong, Ken-Tsung,Chien, Yuh-Yih,Chen, Ruei-Tang,Wang, Chung-Feng,Lin, Yu-Ting,Chiang, Huo-Hsien,Hsieh, Ping-Yuan,Wu, Chung-Chih,Chou, Chung Hsien,Su, Yuhlong Oliver,Lee, Gene-Hsiang,Peng, Shie-Ming
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p. 11576 - 11577
(2007/10/03)
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- Synthesis and properties of 9,9-diarylfluorene-based triaryldiamines
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(matrix presented) 9,9-Diaryl-2,7-dibromofluorene was synthesized by a triflic acid promoted Friedel-Crafts reaction. Introduction of diarylamino groups at its C2 and C7 positions by a Pd-catalyzed amination results in the formation of a novel class of triaryldiamines. The 9,9-diaryl substituents at the central linkage play a less important role in the photophyscial properties but affect the oxidation potential and improve the morphological stability of these new triarylamines.
- Wong, Ken-Tsung,Wang, Zi-Jien,Chien, Yuh-Yih,Wang, Chien-Lung
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p. 2285 - 2288
(2007/10/03)
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- Polyfluorenes with polyphenylene dendron side chains: Toward non-aggregating, light-emitting polymers
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A polyfluorene 12 has been prepared in which bulky polyphenylene dendrimer substituents suppress formation of long wavelength emitting aggregates, thus giving a polymer with pure blue emission. Absorption-and emission spectra and molecular modeling confirm that the bulky dendrimer side chains do not cause extra torsion between the fluorene units. New polyfluorenes with 9,9-diaryl substituents have been prepared to determine the minimum size of substituent necessary for aggregation suppression. An LED using 12 has been demonstrated to produce blue emission with onset voltages below 4 V.
- Setayesh,Grimsdale,Weil,Enkelmann,Muellen,Meghdadi,List,Leising
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p. 946 - 953
(2007/10/03)
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