Deuterium kinetic isotope effects in homogeneous decatungstate catalyzed photooxygenation of 1,1-diphenylethane and 9-methyl-9H-fluorene: Evidence for a hydrogen abstraction mechanism
The homogeneous decatungstate W10O324- catalyzed photooxygenation of 1,1-diphenylethane and 9-methyl-9H-fluorene has been studied mechanistically. The primary and β-secondary kinetic isotope effects provide strong evidence for a stepwise mechanism, with a hydrogen atom abstraction in the rate-determining step.
Lykakis, Ioannis N.,Orfanopoulos, Michael
p. 7835 - 7839
(2007/10/03)
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