Synthesis and structure of 2-phenylanthra[9,1-bc]pyrrol-6-one
Reduction of anti-1-benzoylanthraquinone oxime gave 2-phenylanthra[9,1-bc] pyrrol-6-one whose structure was determined by X-ray analysis. The molecule of 2-phenylanthra[9,1-bc]pyrrol-6-one is almost planar, and its crystalline structure is characterized b
Chirkova,Denisov, V. Ya.,Gatilov, Yu. V.,Bagryanskaya,Rybalova
Radical Alkyne peri-Annulation Reactions for the Synthesis of Functionalized Phenalenes, Benzanthrenes, and Olympicene
Radical cyclization reactions at a peri position were used for the synthesis of polyaromatic compounds. Depending on the choice of reaction conditions and substrate, this flexible approach led to Bu3Sn-substituted phenalene, benzanthrene, and olympicene derivatives. Subsequent reactions with electrophiles provided synthetic access to previously inaccessible functionalized polyaromatic compounds.
Tsvetkov, Nikolay P.,Gonzalez-Rodriguez, Edgar,Hughes, Audrey,dos Passos Gomes, Gabriel,White, Frankie D.,Kuriakose, Febin,Alabugin, Igor V.
p. 3651 - 3655
(2018/03/06)
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