- One-Pot Self-Assembly of Stellated Metallosupramolecules from Multivalent and Complementary Terpyridine-Based Ligands
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A series of stellated metallosupramolecular architectures have been assembled through three-component integrative self-sorting. Building on the complementary ligand pairing, the initial attempts to synthesize the hexagram complex from a combination of X-s
- Chan, Yi-Tsu,Chen, Yu-Sheng,Fu, Jun-Hao,Prusty, Soumyakanta,Wang, Shih-Yu
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supporting information
(2019/10/08)
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- Nickel hemiporphyrazines as bisdienes and bisdienophiles: synthesis and characterization
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The bisdienophilic (hemiporphyrazinatojnickel complexes 1a-d bearing various alkoxy groups were synthesized from diiminoisoindoles 9a-d, diaminopyridines 10a, d, and nickel acetate. Reaction of 1a-d with an excess of pentaene 3 delivered the macrocyclic bisdienes 2a-d. The hemiporphyrazines were characterized by 1H- and 13C-NMR spectroscopy. The NMR spectra of the 1,6,16,21-tetrabutoxy-substituted compounds 1b and 2b are discussed with respect to the presence of syn/anti isomers. VCH Verlagsgesellschaf; mbH, , 1996.
- Rack, Michael,Hauschel, Bernd,Hanack, Michael
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p. 237 - 242
(2007/10/02)
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- TETRAHALOBENZENES AS DI-ARYNE EQUIVALENTS IN POLYCYCLIC ARENE SYNTHESIS
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1,2,4,5-Tetrabromobenzenes and analogous naphthalenes react with one or two equivalents of n-butyllithium and various dienes (furans, pyroles, cyclopentadienes, fulvenes) to form mono- or bis-cycloadducts.Highly substituted arenes can be obtained by removing the oxygen or nitrogen bridges from the furan or pyrrole adducts.By choice of conditions, two identical or two different rings can be fused to the di-aryne equivalent.Improved short syntheses of permethylnaphthalene, -anthracene and -naphthacene are described.A new triphenylene synthesis is presented.
- Hart, Harold,Lai, Chung-yin,Nwokogu, Godson Chukuemaka,Shamouilian, Shamouil
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p. 5203 - 5224
(2007/10/02)
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