Reactions of dibenzoyldiazene. Part 2. Thermal and photochemical decompositions in benzene solution
E.s.r. and microsecond flash-photolysis studies indicate that in benzene solution hydrazyl radicals formed by the addition of various precursors radicals to dibenzoyldiazine are deactivated through a second-order process, yielding the corresponding hydrazines.This process occurs in parallel with a pseudo-first order reaction with dibenzoyldiazene in which an oxygen atom is transferred, yielding the corresponding hydrazoxyl radical and diphenyloxadiazole.A structure-reactivity correlation is noted, and the role played by these in the inhibition and retardation of the radical polymerization of vinyl monomers is discussed.
Bassam, Farideh,Jones, Richard G.,Perrins, Carole M.
p. 1767 - 1772
(2007/10/02)
Reactions of Dibenzoyldiimide with Alkoxide
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Bumgardner, Carl L.,Purrington, Suzanne T.,Huang, Pi-Tsan
p. 2287 - 2289
(2007/10/02)
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