- Thioether profragrances: Parameters influencing the performance of precursor-based fragrance delivery in functional perfumery
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A series of thioether profragrances was prepared by reaction of different sulfanylalkanoates with δ-damascone and tested for their release efficiencies in a fabric-softener and an all-purpose cleaner application. Dynamic headspace analysis on dry cotton and on a ceramic plate revealed that the performance of the different precursors depended on the structure, but also on the particular conditions encountered in different applications. Moreover, profragrances derived from other α,β-unsaturated fragrance aldehydes and ketones were synthesized analogously and evaluated using the same test protocol. Thioethers were found to be suitable precursors to release the corresponding fragrances, but neither the quantity of profragrance deposited from an aqueous environment onto the target surface, nor the amount of fragrance released after deposition could be linearly correlated to the hydrophilicity or hydrophobicity of the compounds. Different sets of compounds were found to be the best performers for different types of applications. Only one of the compounds evaluated in the present work, namely the thiolactic acid derivative of δ-damascone, efficiently released the corresponding fragrance in both of the tested applications. Profragrance development for functional perfumery thus remains a partially empirical endeavour. More knowledge (and control) of the various application conditions are required for an efficient profragrance design.
- Maddalena, Umberto,Trachsel, Alain,Fankhauser, Peter,Berthier, Damien L.,Benczdi, Daniel,Wang, Wei,Xi, Xiujuan,Shen, Youqing,Herrmann, Andreas
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p. 1700 - 1733
(2015/02/19)
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- COMPOUNDS FOR A CONTROLLED RELEASE OF ACTIVE PERFUMING MOLECULES
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The present invention relates to the field of perfumery. More particularly, it concerns compounds comprising at least one β-thio carbonyl or nitrile moiety capable of liberating an active molecule selected from an α,β-unsaturated ketone, aldehyde or nitrile. The present invention concerns also the use of said compounds in perfumery as well as the perfuming compositions or perfumed articles comprising the invention's compounds. (I) wherein: a) m represents an integer from 1 to 6; b) Pro represents a hydrogen atom or a group susceptible of generating an odoriferous α,β-unsaturated ketone, aldehyde or nitrile and is represented by the formulae (II) or (II') in which the wavy line indicates the location of the bond between said Pro and the sulfur atom S; and at least one of the Pro groups is of the formula (II) or (II').
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Page/Page column 25-26
(2013/10/08)
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- AGENT FOR PERMANENT HAIR PROCESSING
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An agent for permanent hair processing is disclosed that can shape the hair even in a neutral to slightly acidic pH region. The agent contains one or more compounds represented by the following formula (1) and/or formula (2): (1) wherein R1 is a hydrogen atom or an alkyl group of 1 to 5 carbon atoms, R2 is an alkoxyalkyl group having a total of 3 to 15 carbon atoms, and the alkylene portion of R2 may contain an ether bond(s); (2) wherein R3 is an alkoxyalkyl group having a total of 3 to 15 carbon atoms, and the alkylene portion of R3 may contain an ether bond(s).
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Page/Page column 20
(2008/06/13)
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