- Synthesis and structures of isomerically pure bis-(alkylbenzo) crown ethers
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A convenient method for the synthesis of bis-(4-alkyl-2-hydroxyphenoxy) alkoxy ethers, precursors to highly lipophilic, alkylbenzo-substituted crown ethers, is described. Thirteen isomerically-pure, bis-t-alkylbenzo crown ethers were prepared. The solid-state structures of three representative, bis-t-octylbenzo crown ethers are reported, representing the first structures ever reported for t-octylbenzocrown ethers.
- Sachleben, Richard A.,Bryan, Jeffrey C.,Lavis, Jerome M.,Starks, Courtney M.,Burns, John H.
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p. 13567 - 13582
(2007/10/03)
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