Thermal desulfurization of (Alkoxymethyl)thiiranes
Reaction of (alkoxymethyl)oxiranes with thiourea in methanol has afforded the corresponding thiiranes, and catalyst-free thermal desulfurization of the products has been studied. The major products of desulfurization are alcohols and alkenes, both in the cases of (polyfluoroalkyloxymethyl)thiiranes and their non-fluorinated analogs. Longer alkyl chain in thiiranes favors formation of alcohols over alkenes formation in the course of desulfurization.
Nalet'Ko,Pervova,Gorbunova,Zapevalov, A. Ya,Toporova,Saloutin
p. 2120 - 2124
(2015/02/02)
Promising prospects for using partially fluorinated alcohols as O-nucleophilic reagents in organofluoric synthesis
Perfluoroolefins react with isopropyl alcohol under the conditions of radical initiation to form partially fluorinated aliphatic alcohols. The reactions of these alcohols with hexafluoropropylene and compounds containing labile halogen atoms (in particular, with allyl bromide and epichlorohydrin) were studied.
Il'in,Il'in,Bakhmutov,Furin,Pokrovskii
p. 405 - 418
(2008/02/02)
FLUORINE-CONTAINING 2,3-EPOXYPROPYL ETHERS. SYNTHESIS AND SPECTRAL CHARACTERISTICS
Polyfluoroalkyl 2,3-epoxypropyl ethers were prepared by the reactions of fluoro olefins with 2,3-epoxy-1-propanol in presence of potassium fluoride and under the conditions of phase-transfer catalysis. 1H and 19F NMR- and mass-spectral characteristics of the polyfluoroalkyl ethers were determined.
Solov'ev, D. V.,Kolomenskaya, L. V.,Rodin, A. A.,Zenkevich, I. G.,Lavrent'ev, A. N.
p. 611 - 615
(2007/10/02)
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