Synthetic studies towards western and eastern macropolypeptide subunits of Kistamycin
The western subunit (fused bicyclic 16+15 membered ring) was synthesized by sequential intramolecular S(N)Ar reaction and the first 17-membered ring compound as model of the eastern subunit was obtained by an intramolecular Ni0 mediated coupling reaction.
The first synthesis of 16+15-membered bicyclic polypeptide model of A- O-C-B-O-D rings of kistamicin
A 16+15 membered bicyclic polypeptide containing biaryl ether bonds, model of A-O-C-B-O-D rings of kistamicin has been synthesized by sequential intramolecular SN(Ar) reactions.
Beugelmans, Rene,Gonzalez Zamora, Eduardo,Roussi, Georges
p. 8189 - 8192
(2007/10/03)
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