Zinc, cadmium, and mercury complexes with fluorinated selenolate ligands
Reductive cleavage of C6F5SeSeC6F 5 with elemental M (M = Zn, Cd, and Hg) in pyridine results in the formation of (py)2Zn(SeC6F5)2, (py)2Cd(SeC6F
Emge, Thomas J.,Romanelli, Michael D.,Moore, Brian F.,Brennan, John G.
p. 7304 - 7312
(2010/09/16)
Synthesis, chemistry, and characterization of perfluoroaromatic selenium derivatives
The reaction of perfluoroaryllithium RC6F4Li, where R = F or 4- CF3C6F4O, respectively, with selenium gives the known diselanes (RC6F4Se)2 (1a, 1b). Redox reactions of
Klapoetke, Thomas M.,Krumm, Burkhard,Polborn, Kurt
p. 1359 - 1366
(2007/10/03)
A New Synthetic Route for the Preparation of Perfluoroorganoselenium and-tellurium Compounds
A new synthetic route for the preparation of perfluoroorganoselenium and-tellurium compounds is presented. By the reaction of disodiumchalcogen ides Na2Ex (x=1, 2; E=Se, Te) with C6F5X or C2F5X (X=Br, I) in liquid ammonia, thf of dmf the corresponding selenium and tellurium compounds areobtained in good yields. The reaction conditions are described.
Kasemann, R.,Lichenheim, C.,Nowicki, G.,Naumann, D.
(2008/10/08)
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