Alkyl-2-hydroxyalkyl sulfides and their oxyalkylenated adducts were obtained in the reaction of oxirane or methyloxirane with C4-C12 alkylthiols in presence of basic or acidic catalysts.The sulfides were further oxidized to sulfoxides and sulfones.
Chlebicki, Jan,Cichacz, Zbigniew
p. 485 - 494
(2007/10/02)
Functional organic peroxides. XVII. Sulfonyl-containing dialkyl peroxides
High-boiling sulfonyl-containing dialkyl peroxides (initiators of cross-linking processes in saturated elastomers) are formed during the alkylation of tert-butyl hydroperoxides by 2-chloroethyl alkyl sulfones in the presence of alkali.Comparison of the kinetic parameters of the thermal decomposition of C8H17SO2CH2CH2OOC(CH3)3 and di-tert-butyl peroxide shows that the sulfonyl-containing fragment removed to the β position does not affect the thermal stability of the peroxide bond.The main reaction of the radical C8H17SO2CH2CH2O. generated during thermolysis is the abstraction of a hydrogen atom from the solvent.
Rakhimov, A. I.,Shatalin, Yu. V.,Baklanov, A. V.,Derzhinskii, A. R.,Konyushkin, L. D.,et al.
p. 1708 - 1711
(2007/10/02)
FUNCTIONAL SULFUR-CONTAINING COMPOUNDS. 4. PREPARATION OF CHLORO(BROMO)ALKYL SULFONES BY OXIDATIVE HALOGENATION OF HYDROXYALKYL SULFIDES AND SULFOXIDES WITH MIXTURES OF HYDROGEN PEROXIDE AND A HYDROHALIC ACID
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Derzhinskii, A. R.,Konyushkin, L. D.,Prilezhaeva, E. N.
p. 995 - 1001
(2007/10/02)
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