This invention describes reagent precursors and methods for chemical and biochemical reactions. These reagent precursors that can be activated in solution upon irradiation to generate reagents required for the subsequent chemical reactions. Specifically, photogenerated reagents (PGR) are useful for controlling parallel combinatorial synthesis and various chemical and biochemical reactions.
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Page/Page column 20
(2008/06/13)
An appraisal of new variants of Dde amine protecting group for solid phase peptide synthesis
A series of new variants of Dde, substituted at the exocyclic alkene position have been developed and their application in solid phase peptide synthesis assessed. The new derivatives offer complete resistance towards 20% piperidine in DMF and provide a considerable barrier towards N→N'-intramolecular migration.
Chhabra, Siri Ram,Hothi, Bhupinder,Evans, David J.,White, Peter D.,Bycroft, Barrie W.,Chan, Weng C.
p. 1603 - 1606
(2007/10/03)
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