Synthesis and electrode properties of 16-membered azo- and azoxycrown ethers. Structure of tribenzo-16-azocrown-6
16-Membered benzoazo- and benzoazoxycrown ethers have been synthesized by reductive macrocyclization of respective bis(nitrophenoxy)oxaalkanes. The isomers of azocrown ethers were separated and E and Z structures were ascribed. Behavior of the compounds as ionophores in ion-selective membrane electrodes has been studied. Structure of Z isomer of 16-membered tribenzoazocrown ether has been determined.
Luboch, Elzbieta,Biernat, Jan F.,Simonov, Yurii A.,Dvorkin
p. 4977 - 4990
(2007/10/03)
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