- Method for synthesize aryltris (tri-R-siloxanyl) silane
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The invention relates to the technical field of organic chemistry. In order to solve the problem of complex steps in the process of synthesizing aryltris (tri-R-siloxanyl) silane,the invention provides a method for synthesizing aryltris (tri-R-siloxanyl) silane. An organic solvent is used as solvent, trialkylsilane and hydrogen peroxide react for 1-2 hours, then triethylamine and aryltrichlorosilane are respectively added, and the mixture is allowed to react for 1-5 hours, organic phase is filtered and concentrated to obtain aryltris (tri-R-siloxanyl) silane. The method adopts one pot reaction, which has the advantages of mild conditions, high yield and high product purity, and the process is simple.
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Paragraph 0025; 0026
(2019/01/08)
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- Selective hydrosiloxane synthesis: Via dehydrogenative coupling of silanols with hydrosilanes catalysed by Fe complexes bearing a tetradentate PNNP ligand
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A well-defined iron complex system was established using PNNP-R (R = Ph and Cy) as a strong σ-donating ligand with a rigid meridional tetradentate structure. Reactive Fe(0) complexes [{Fe(PNNP-R)}2(μ-N2)] were synthesized by a reaction of the corresponding iron dihalide with NaBEt3H and structurally characterized. The reaction proceeded via the iron dihydride intermediate [Fe(H)2(PNNP-R)], which underwent H2 reductive elimination, supporting the hemilabile behavior of PNNP-R. [{Fe(PNNP-R)}2(μ-N2)] catalyzed the dehydrogenative coupling of silanols with silanes to selectively form various hydrosiloxanes, which are important building blocks for the synthesis of a range of siloxane compounds. This system exhibited higher catalytic efficiency than the previously reported precious-metal-catalyzed systems.
- Takeshita, Tomohiro,Sato, Kazuhiko,Nakajima, Yumiko
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p. 17004 - 17010
(2019/01/03)
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- Synthetic method of allyl acrylate
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The invention discloses a new synthetic method of allyl acrylate. According to the method, an organic silicon monomer with functional groups is used, and the allyl acrylate is prepared under the soft reaction condition. The synthetic method of the allyl acrylate includes three steps that (1) acryloxytrimethylsilane is synthesized; (2) allyloxy silane is synthesized; and (3) the acryloxytrimethylsilane and the allyloxy silane are mixed. According to the raw materials used in a reaction, chlorine elements are fully converted into inorganic salt, low-boiling-point chloride like phosphorus trichloride is not used, and it is guaranteed that the chlorine elements are not contained in a prepared product; reaction conditions are soft, and the requirement for the equipment is not high; purification is easy, boiling points of all components are large in difference, and reduced pressure distillation separation is easy; water washing is not needed, and amplification is easy; and trifluoromethanesulfonic acid serves as a catalyst, the high acidity is achieved, and double bonds cannot be damaged.
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Paragraph 0019
(2017/04/28)
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- Method for producing polyimidesiloxane
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PROBLEM TO BE SOLVED: To provide a method for synthesizing siloxanes at will in good yield while maintaining high structural controllability, which can be applied to substrates having various substituents.SOLUTION: The method comprises reacting benzyloxysilanes and silicon halides in the absence of hydrogen using a catalyst comprising a transition metal or a compound thereof, preferably a metal of group 9 or group 10 of the periodic table or a compound thereof. Thereby, corresponding siloxanes can be produced safely and simply in high yield under a mild reaction condition accompanied by elimination of a benzyl halide. Especially, by using an active carbon-supported catalyst as a heterogeneous catalyst, the target siloxanes can be separated easily.
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Paragraph 0046
(2018/10/16)
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- In a method of manufacturing a condition anhyride silanolated
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PROBLEM TO BE SOLVED: To provide a method capable of synthesizing silanol under an anhydrous condition and a mild condition, adapting to substrates having various substituents, and producing siloxanes freely at an excellent yield, while having high structure controllability.SOLUTION: By a hydrogen addition reaction in which benzyloxy-substituted silanes are used as a silanol precursor, and a metal in the group 9 or 10 on the periodic table or a metal compound is used as a catalyst, corresponding silanols can be produced safely and easily at a high yield under an anhydrous condition and a mild condition, and especially object silanols can be isolated easily by using a carbon-carrying catalyst.
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Paragraph 0034
(2018/03/24)
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- Pd/C-catalyzed cross-coupling reaction of benzyloxysilanes with halosilanes for selective synthesis of unsymmetrical siloxanes
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A new protocol for the nonhydrolytic synthesis of unsymmetrical siloxanes has been developed. The cross-coupling reaction of benzyloxysilanes with halosilanes catalyzed by Pd/C afforded various unsymmetrical siloxanes with co-production of benzyl halides. the Partner Organisations 2014.
- Igarashi, Masayasu,Kubo, Keiko,Matsumoto, Tomohiro,Sato, Kazuhiko,Ando, Wataru,Shimada, Shigeru
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p. 19099 - 19102
(2014/05/20)
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- Cosmetic composition comprising a volatile fatty phase
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The invention relates to a composition comprising, in a physiologically acceptable medium, a volatile silicone fatty phase comprising at least one non-cyclic volatile silicone oil, wherein the volatile silicone fatty phase has an evaporation profile such that the mass of the at least one volatile silicone oil evaporated after 30 minutes is from 2 mg/cm2 to 9 mg/cm2. The invention also relates to making up and caring for human keratin materials using the inventive compositions.
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- Phenylsilanetriol - Synthesis, stability, and reactivity
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Crystalline phenylsilanetriol, PhSi(OH)3 (1) was obtained by smooth hydrolysis of phenyltrimethoxysilane and characterised by different analytical methods (wide angle X-ray powder diffraction, NMR, IR, thermogravimetric analysis). The title-compound is surprisingly stable in the solid state but slowly condenses in acetone solution. Reaction of 1 with Me3SiCl and Me2(CH2 Cl)SiCl gave the corresponding tris-triorganylsiloxy substituted derivatives in high yields.
- Korkin,Buzin,Matukhina,Zherlitsyna,Auner,Shchegolikhina
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p. 313 - 320
(2007/10/03)
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- Method for the cleavage of organic siloxanes, and products and applications thereof
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A method for the cleavage of organosiloxanes with chlorosilanes in the presence of ferric chloride and hydrogen chloride as catalysts resulting in chloroalkyl silanes or chloroaryl silanes, and organosiloxanes, which are characterized by one or more --O--Si--R3 groups, (R=alkyl or aryl), which are directly bound to a silicon atom which in turn is bound either to the same grouping or to an alkyl or aryl moiety.
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