REARRANGEMENT OF RADICALS IN THE HOMOLYTIC ADDITION OF m-XYLENE TO METHYL METHACRYLATE
Investigation of the products from the reaction of m-xylene with methyl methacrylate under the conditions of thermal and peroxide initiation led to the isolation and identification of compounds which indicated that rearrangement of the intermediate radical-adducts occured in addition to the main process.The rearrangement takes place mainly with 1,5-H migration, but 1,3-H migration also takes place at high temperatures (350 deg C).
Galust'yan, G. G.
p. 1065 - 1067
(2007/10/02)
On the structure elucidation of niphimycin. Part I. Purification and characterization of the niphimycins Iα and Iβ: Degradation by nitric acid
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Bassi,Joos,Gassmann,et al.
p. 92 - 117
(2007/10/02)
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