Synthesis of 6-methyl-8H-dibenzo[a,g]quinolizin-8-imines via Reissert compounds
Alkylation of Reissert compounds derived from 3-methylisoquinolines with several 2-cyanobenzylbromides followed by hydrolytic cleavage provided the corresponding 1-benzyl-3-methylisoquinolines. Treatment of the latter with methylmagnesiumiodide caused cyclization to the title compounds rather than formation of 2-acetylbenzylisoquinolines.
Reimann, Eberhard,Hertel, Rainer,Krauss, Juergen
experimental part
p. 673 - 684
(2009/07/18)
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