Solvent-free chelation-assisted intermolecular hydroacylation: Effect of microwave irradiation in the synthesis of ketone from aldehyde and 1-alkene by Rh(I) complex
As a green alternative to classical homogeneous catalyst in toluene in closed vessels, the intermolecular hydroacylation of 1-alkenes with aldehydes by Rh(I) complex (Wilkinson catalyst) can be realized efficiently under solvent-free conditions. When coupled to microwave activation, it results in a serious improvement when compared to classical conditions.
A highly active catalyst system for intermolecular hydroacylation
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Jun, Chul-Ho,Lee, Dae-Yon,Lee, Hyuk,Hong, Jun-Bae
p. X3070-3072
(2007/10/03)
Catalytic transformation of aldimine to ketimine by Wilkinson's complex through transimination
(equation presented) The C-H bond activation in homogeneous catalysis is important for carbon skeleton construction through C-C bond formation. In this report, a new direct synthesis of ketimine from aldimine bearing no coordination site is demonstrated with high catalytic efficiency. Transimination is the major role for this catalytic reaction.
Jun, Chul-Ho,Hong, Jun-Bae
p. 887 - 889
(2008/02/10)
Direct Synthesis of Ketones from Primary Alcohols and 1-Alkenes
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Jun, Chul-Ho,Huh, Chan-Woo,Na, Sang-Jin
p. 145 - 147
(2007/10/03)
Chelation-Assisted Intermolecular Hydroacylation: Direct Synthesis of Ketone from Aldehyde and 1-Alkene
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Jun, Chul-Ho,Lee, Hyuk,Hong, Jun-Bae
p. 1200 - 1201
(2007/10/03)
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