Generation of electrophilic iodine from iodine monochloride in neutral media. Iodination and protodeiodination of carbazole
In reaction of iodine monochloride with CF3COOAg, CH 3COONa or (CH3COO)2Pb in acetonitrile and acetic acid the chloride is bonded by metal cations, and electrophilic iodine is generated able to easily iodinate a
Filimonov,Krasnokutskaya,Lesina
p. 875 - 880
(2007/10/03)
Iodine Cyanide Promoted Iodination of Aromatic Compounds. A Simple Synthesis of 1-Iodopyrene
A simple method for the iodination of reactive aromatic compounds, using ICN in the presence of a Lewis acid as the source of iodine, is presented. 1-Iodopyrene is obtained in 81percent isolated yield from the reaction of pyrene and ICN with AlCl3 in CH3NO2/(C2H5)2O.Anthracene undergoes partial chlorination in the presence of AlCl3, but with BF3, 9-iodoanthracene is obtained in 48percent isolated yield.
Radner, Finn
p. 481 - 484
(2007/10/02)
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