Directed γ-C(sp3)-H Alkylation of Carboxylic Acid Derivatives through Visible Light Photoredox Catalysis
Visible light photoredox catalysis enables direct γ- C(sp3)-H alkylation of saturated aliphatic carbonyl compounds. Electron-deficient alkenes are used as the coupling partners in this reaction. Distinguished site selectivity is controlled by the predominant 1,5-hydrogen atom transfer of an amidyl radical generated in situ.
Chen, Dian-Feng,Chu, John C. K.,Rovis, Tomislav
p. 14897 - 14900
(2017/10/31)
REACTIONS OF Fe(II)-COORDINATED MONOCARBONITRILES AND MONOCARBOXAMIDES
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Vorob'eva, E. M.,Litvyak, I. G.,Sumarokova, T. N.
p. 2043 - 2048
(2007/10/02)
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