- Soluble precursors of 2,3-naphthalocyanine and phthalocyanine for use in thin film transistors
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Soluble precursors of 2,3-naphthalocyanine (Nc) and phthalocyanine (Pc) were prepared and were converted into insoluble semiconducting thin films of Pc and Nc by heating after fabrication via spin-coating. The Royal Society of Chemistry.
- Hirao, Atsuko,Akiyama, Taiji,Okujima, Tetsuo,Yamada, Hiroko,Uno, Hidemitsu,Sakai, Yoshimasa,Aramaki, Shinji,Ono, Noboru
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- The synthesis of metal-free phthalocyanines from phthalonitriles with hexamethyldisilazane
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Metal-free phthalocyanines were prepared in good yields by heating phthalonitriles with hexamethyldisilazane, (NH4)2SO 4, and DMF. Good yields of metal-free phthalocyanines involving peripherally substituted phthalocyanines were attained with a catalytic amount of hexamethyldisilazane. Naphthalocyanine was also prepared. Additional additives were examined to accelerate the formation of the phthalocyanine framework.
- Uchida, Hitoshi,Yoshiyama, Hideyuki,Reddy, Paidi Yella,Nakamura, Shuichi,Toru, Takeshi
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- Novel Synthesis of Metal-Free Phthalocyanines from Phthalimides and Phthalic Anhydrides with Hexamethyldisilazane
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Metal-free phthalocyanines and their peripherally substituted derivatives have been synthesized from unsubstituted and substituted phthalimides, phthalic anhydrides, and naphthalimide on heating with hexamethyldisilazane under mild conditions.
- Uchida, Hitoshi,Yoshiyama, Hideyuki,Reddy, Paidi Yella,Nakamura, Shuichi,Toru, Takeshi
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- FLUORESCENCE LABELING AGENT, PHOTODYNAMIC THERAPEUTIC AGENT AND PHTHALOCYANINE
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PROBLEM TO BE SOLVED: To provide a phthalocyanine-based compound having excellent properties such as fluorescence intensity, light resistance and singlet oxygen generation ability suitable for a fluorescence labeling agent and a photodynamic therapeutic agent in a wavelength region of 800 nm or more. SOLUTION: This invention relates to salts of a phosphorus-containing phthalocyanine-based compound in which a phosphorus atom in a phosphorus compound expressed by formula: R5O-P-OR6 is coordinated with a phthalocyanine-based compound, and to a fluorescence labeling agent and a photodynamic therapeutic agent, which contain the salts of the phosphorus-containing phthalocyanine-based compound. In the formula, R5 and R6 are H, an aliphatic hydrocarbon group, -P(=O) R7R8, -C(=O) R9, -S(=O)2R10 or -SiR11R12R13; R7 and R8 are H, OH, an aliphatic hydrocarbon group, an aromatic hydrocarbon group, an alkoxyl group, or an aryloxy group; R9 is H, an aliphatic hydrocarbon group, or an aromatic hydrocarbon group; R10 is OH, an aliphatic hydrocarbon group, or an aromatic hydrocarbon group; and R11 to R13 are an aliphatic hydrocarbon group or an aromatic hydrocarbon group. SELECTED DRAWING: None COPYRIGHT: (C)2021,JPOandINPIT
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Paragraph 0079; 0081
(2021/04/23)
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- Green pigment and use thereof
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[Problem] weather resistance, heat resistance, stability and with a hygienic environment, after dispersion of colors of green pigment free halogen free, using paint, printing ink or toner and. General formula (1) compounds containing a green pigment [a]. [R1 , R6 , R7 , R12 , R13 , R18 , R19 , R24 Is, a hydrogen atom, R2 - R5 , R8 - R11 , R14 - R17 , R20 - R23 Is, a hydrogen atom, a cyano group, a nitro group, an alkyl group of 1 - 5 carbon atoms, an alkenyl group having a carbon number of 1 - 5, 6 - 10 carbon atoms of the aryl group, - OR25 , - COOR26 , - CONHR27 , - NHCOR28 , - SO2 NHR29 Or - NR30 R31 A, R25 - R31 Is, a hydrogen atom, an alkyl group of 1 - 5 carbon atoms, an alkenyl group having a carbon number of 1 - 5, 6 - 10 carbon atoms or aryl groups, X1 The ligands may have one hydrogen atom or 2 manganese, iron, cobalt, nickel, copper or zinc as shown. ] Figure 1 [drawing]
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Paragraph 0113-0114; 0016
(2020/03/23)
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- GREEN PIGMENT FOR PLASTICS, AND COLORING COMPOSITION AND MOLDING THAT USE THE SAME
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PROBLEM TO BE SOLVED: To provide: a halogen-free green pigment for plastics that has all of excellent heat resistance, excellent migration resistance and environmental sanitation; and a green coloring composition and a plastic molding that use the pigment. SOLUTION: The green pigment for plastics comprises, an essential component, a naphthalocyanine compound represented by general formula (1). The coloring composition and the molding use the naphthalocyanine compound represented by general formula (1). SELECTED DRAWING: None COPYRIGHT: (C)2021,JPOandINPIT
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Paragraph 0059; 0074
(2021/01/05)
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- Electrosynthesis of a New Molecular Semiconductor: Lithium Naphthalocyanine Radical
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An electrochemical procedure is used to reduce 2,3-dicyanonaphthalene into the lithium naphthalocyanine radical (NPcLi): a new material with semiconducting properties.
- Petit, Michel A.,Bouvet, Marcel,Nakache, Didier
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p. 442 - 443
(2007/10/02)
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- PREPARATION, SPECTRAL PROPERTIES, AND X-RAY STRUCTURAL FEATURES OF 2,3-NAPHTHALOCYANINES.
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We have prepared a series of 2,3-naphthalocyanine (H//2NPc) compounds and examined their spectroscopic properties. All of them can be vacuum sublimed as thin films which absorb strongly in the near infrared and thus make them potentially useful as optical data recording media. In addition, we have measured the electrical resistivities, at room temperature, of several of the compacted 2,3-naphthalocyanines and find them to be semiconductors. Doping with bromine vapor enhances the conductivities only slightly (H//2NPc actually becomes more resistive).
- Kaplan,Lovinger,Reents Jr.,Schmidt
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p. 345 - 258
(2007/10/02)
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