INFLUENCE OF ELECTRON-WITHDRAWING SUBSTITIUENTS IN THE OXAPHOSPHOLE RING ON THE AXIAL CONFORMATIONAL TRANSMISSION IN P(V) COMPOUNDS
A MNDO and 300-MHz 1H NMR study of some trigonal-bipyramidal (TBP) five-coordinated phosphorus (P(V)) compounds is reported.It is shown by the MNDO calculations that, in the oxaphosphole P(V) TBP compounds 5a-c, the electron distribution in the axial bond
Vries, N. K. De,Buck, H. M.
p. 267 - 280
(2007/10/02)
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