Effect of benzylic methyl groups on kinetic basicity of amine ligand in o-boron substituted N,N-dimethylbenzylamines
Rates of the dissociation of the intramolecular B-N coordination bond in two series of phenylborane derivatives, the boronate and diethylborane complexes, with -CHMeNMe2 or -CMe2NMe2 group at the o-position were determined