A Direct Aromatic Methylsulfanylation of N-Aryl-N-methoxyacetamides with an Aluminium Chloride-Dimethyl Sulfide System
Treatment of N-aryl-N-methoxyacetamides, which bear a strong electron-donating group on the aryl ring, with an AlCl3-Me2S system results in heterocyclic cleavage of the nitrogen-oxygen bond and introduction of a methylsulfanyl group at the ortho or para position of the aryl ring.
The Solvolysis of N-Acetoxy-1-N-acetylaminonaphtalene and N-Acetoxy-2-N-acetylaminonaphtalene: Divergent Chemistry and Mutagenic Activity
Upon solvolysis in neutral 40percent aqueous acetone, N-acetoxy-1-N- and N-acetoxy-2-N-acetylaminonaphtalene exibit completely different modes of reaction; the former reacts with nitrenium ion formation, while the latter undergoes acyl oxygen scission.
Underwood, Graham R.,Davidson, Catherine M.
p. 555 - 556
(2007/10/02)
The Solvolysis of N-Acetoxy-2-acetylaminofluorene and N-Acetoxy-4-acetylaminobiphenyl: Delicate Balance between Nitrenium Ion Formation and Hydrolysis
The solvolysis of N-acetoxy-2-acetylaminofluorene in aqueous acetone at neutral pH proceeds exclusively with nitrenium ion formation while under the same conditions, the 4-aminobiphenyl analogue undergoes exclusive acyl-oxygen scission.
Underwood, Graham R.,Kirsch, Robert B.
p. 136 - 138
(2007/10/02)
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