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2516-97-4

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Versatile synthesis of secondary 2-amino thiols and/or their disulfides via thiazolinium salts
Commercially available β-amino alcohols have been transformed into various secondary β-amino thiols and/or their disulfides by using methyl dithioacetate as a source of sulfur. The transformation involves a thiazolinium salt as a versatile key intermediate, which enables easy modulation of the product structure by varying the substituents on the hetero-cycle and the N-alkylating agent.
Mercey, Guillaume,Lohier, Jean-Francois,Gaumont, Annie-Claude,Levillain, Jocelyne,Gulea, Mihaela
experimental part
p. 4357 - 4364
(2011/02/24)

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Chemical Properties

Melting Point: 118-120°C
Boiling Point: 423.598 °C at 760 mmHg
Flash Point:209.984 °C
Density: 1.474 g/cm³
Storage Temp.:Sealed in dry,Room Temperature
Vapor Pressure: 2.31E-08mmHg at 25°C
Refractive Index: 1.475
PKA: pK1:2.36 (25°C)
BRN: 1760342

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