Spectroscopy and calculations of weakly bound gallium complexes with ammonia and monomethylamine
The adiabatic IPs and intermolecular vibrational frequencies were obtained for the weakly bound gallium-ammonia and -monomethylamine complexes. It was found that the methyl substitution for hydrogen in ammonia enhances the binding of the gallium atom and
Amidoalane, amidogallane and amidoindane, H2MNH2 (M = Al, Ga or In): A matrix study of three prototypal molecules with the potential for M-N multiple bonding
Photolysis of Al, Ga or In atoms (M) isolated in NH3-doped Ar matrices gives first the divalent amido derivative HMNH2 (λ = 436 nm) and then the univalent and trivalent amido derivatives MNH2 and H2MNH2 (λ = 200-800 nm); the measured and calculated properties of H2MNH2 are outlined.
Himmel, Hans-Joerg,Downs, Anthony J.,Greene, Tim M.
p. 871 - 872
(2007/10/03)
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