- Reversible Photocontrolled Nanopore Assembly
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Self-assembly is a fundamental feature of biological systems, and control of such processes offers fascinating opportunities to regulate function. Fragaceatoxin C (FraC) is a toxin that upon binding to the surface of sphingomyelin-rich cells undergoes a s
- Mutter, Natalie L.,Volari?, Jana,Szymanski, Wiktor,Feringa, Ben L.,Maglia, Giovanni
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supporting information
p. 14356 - 14363
(2019/10/11)
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- A novel photochromic azobenzene compound and its synthetic method
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The invention provides a novel photochromic azobenzene compound and a synthesis method thereof and relates to a novel compound N-[4-[2-(4-methoxyphenyl) diazenyl] phenyl]-2-nitroaniline with a photochromic property and a synthesis method of the novel compound. The synthesis method comprises diazonium coupling reaction and coupling reaction between aromatic amine and aromatic halides. According to the invention, coupling reaction conditions of aromatic amine and aromatic halides are very simple, to be specific, only alkali metal fluorides with equal molar mass are added into reaction liquid, and reflux is carried out at 130 DEG for 3 h; a solvent is not required to be subjected to anhydrous anaerobic treatment, that reaction is carried out under nitrogen or argon atmosphere is not required, no side reaction is generated, aftertreatment of the product is simple, the conversion rate is higher, the yield of the target product is 48-74%, in addition, equipment adopted by the invention is relatively simple, the cost is low, and obvious economic benefits and environment-protection benefits are realized. The defects, in the prior art, that coupling reaction between aromatic amine and aromatic halides can be carried out at high temperature, with existence of inorganic base and under anhydrous anaerobic inert atmosphere usually, the reaction time is long, side reaction is multiple and the yield is low are overcome.
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Paragraph 0044; 0046; 0047
(2017/08/24)
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- Azo dichroic dye (by machine translation)
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PROBLEM TO BE SOLVED: has a wide absorption characteristics in the visible light region, order parameter (S) is high, a good solubility in organic solvents of azo dichroic dye. SOLUTION: azo eq. (1) represented by the dichroic dye. [Bz benzene ring; m the 1-5 integer; R 1-R 4 are each independently H or alkyl group; R 1 and R 3 or R 2 and R 4 are coupled to a benzene ring may form; however, m pieces of Bz, at least one of the inner Bz in, R 1 and R 2 alkyl group; R 3 and R 4 the H; B is an aromatic ring group; A is a substituted phenyl group or Benzothiazolesulfonamide-2-yl group] selected drawing: no (by machine translation)
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Paragraph 0136-0138
(2018/09/02)
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- Rapid and direct spectrophotometric method for kinetics studies and routine assay of peroxidase based on aniline diazo substrates
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Peroxidases are ubiquitous enzymes that play an important role in living organisms. Current spectrophotometrically based peroxidase assay methods are based on the production of chromophoric substances at the end of the enzymatic reaction. The ambiguity regarding the formation and identity of the final chromophoric product and its possible reactions with other molecules have raised concerns about the accuracy of these methods. This can be of serious concern in inhibition studies. A novel spectrophotometric assay for peroxidase, based on direct measurement of a soluble aniline diazo substrate, is introduced. In addition to the routine assays, this method can be used in comprehensive kinetics studies. 4-[(4-Sulfophenyl)azo]aniline (λ max = 390 nm, ? = 32 880 M?1 cm?1 at pH 4.5 to 9) was introduced for routine assay of peroxidase. This compound is commercially available and is indexed as a food dye. Using this method, a detection limit of 0.05 nmol mL?1 was achieved for peroxidase.
- Mirazizi, Fatemeh,Bahrami, Azita,Haghbeen, Kamahldin,Shahbani Zahiri, Hossein,Bakavoli, Mehdi,Legge, Raymond L.
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p. 1162 - 1169
(2016/10/09)
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- Chromium complex compound
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A chromium complex compound represented as the free acid form by the formula (I): STR1 wherein X1 represents a hydrogen atom, a methyl group, a methoxy group or a sulfonic acid group; X2, X3 and X4 represent independently a hydrogen atom, a chlorine atom, a methyl gorup, a methoxy group, a carboxyl group or a sulfonic acid group; Y represents a hydrogen atom or a sulfonic acid group; Z represents a chlorine atom, a fluorine atom or --N30 (R)3 (R represents a C1 to C4 -alkyl group), STR2 and M represents a hydrogen atom or an alkali metal, a process for producing the chromium complex compound (I) and a method for dyeing cellulosic fibers with the same. The chromium complex compound represented by formula (I) is excellent in affinity to cellulosic fibers and in color-yield, build-up properties and fastness properties. These compounds are dyes for cellulosic fibers.
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