- Safe and Convenient Synthesis of Primary N -Nitramines in the Freon Media
-
A convenient one-pot synthesis of primary aliphatic N-nitramines, which includes the nitration of available N,N′-dialkyloxalamides or N-alkylcarbamates with dinitrogen pentoxide in the 1,1,1,2-tetrafluoroethane media followed by ammonolysis of intermediate N-nitroamides in the same solvent has been developed. The method is environmentally safe, and affords target N-nitramines in up to 94% overall yield.
- Zharkov, Mikhail N.,Kuchurov, Ilya V.,Fomenkov, Igor V.,Tartakovsky, Vladimir A.,Fedyanin, Ivan V.,Zlotin, Sergei G.
-
supporting information
p. 1103 - 1108
(2017/02/24)
-
- Nitration of carbonic, sulfuric and oxalic acid-derived amides in liquid carbon dioxide
-
N-Nitro- and N,N'-dinitroamides of carbonic, sulfuric and oxalic acids have been prepared in 76-99% yield by the nitration of the corresponding amides with dinitrogen pentoxide in liquid carbon dioxide.
- Kuchurov, Ilya V.,Fomenkov, Igor V.,Zlotin, Sergei G.,Tartakovsky, Vladimir A.
-
-