- Facile synthesis of triarylmethanimine promoted by a lewis acidbase pair: Theoretical and experimental studies
-
An efficient method for triarylmethanimine synthesis promoted by a Lewis acidbase pair (AlCl3Et3N) was designed using mechanistic analysis with the aid of density functional theory. A series of triarylmethanimines were successfully prepared under mild con
- Liu, Yan,Yang, Qiwu,Hao, Dongling,Zhang, Wenqin
-
p. 1390 - 1395,6
(2020/09/02)
-
- Reactions of aniline with alkali metal diphenylketyls and dianions derived from benzophenone and Michler's ketone
-
Potassium diphenylketyl and benzophenone dianion react with aniline to afford N-(diphenylmethylene) aniline. Under analogous conditions, the corresponding sodium and lithium derivatives undergo disproportionation with formation of triphenylmethanol, benzo
- Turaeva,Kurbatov
-
p. 1787 - 1790
(2007/10/03)
-
- Silver(I) Ion Mediatied Desulfurization-Condensation of Thiocarbonyl Compounds with Several Nucleophiles
-
The desulfurization-condensation reaction was investigated in the presence of silver(I) salt for several kinds of thiocarbonyl compounds with nucleophiles.Such thiocarbonyl compounds as 4,4'-bis(dimethylamino)thiobenzophenone, ethylene trithiocarbonate, and N-(thiobenzoyl)morpholine react with malononitrile or other active methylene compounds in the presence of silver trifluoroacetate to afford the corresponding olefinic compounds together with silver sulfide.This reaction of thiocarbonyl compounds with some other nucleophiles such as aniline derivatives and ethylene glycol, has also afforded imines and 1,3-dioxolane derivatives.
- Shibuya, Isao,Taguchi, Yoichi,Tsuchiya, Tohru,Oishi, Akihiro,Katoh, Eisaku
-
p. 3048 - 3052
(2007/10/02)
-