The influence of perfluorinated substituents on the nucleophilic reactivities of silyl enol ethers
The fluorinated trimethylsilyl enol ethers 3a-c were synthesized, and the kinetics of their reactions with the benzhydrylium ions 4 was studied by UV-vis spectroscopy in dichloromethane. Comparison with nonfluorinated analogues shows that replacement of C
Laub, Hans A.,Gladow, Daniel,Reissig, Hans-Ulrich,Mayr, Herbert