Facile generation of a strained cyclic vinyl cation by thermal solvolysis of cyclopent-1-enyl-λ3-bromanes
Last of the cyclic vinyl cations: The simple solvolysis of cyclopent-1 -enyl-13-bromane efficiently generates the highly strained cyclopent-1 -enyl cation at room temperature (see scheme). The very high nucleofugality of the aryl-13-bromanyl groups are re
Miyamoto, Kazunori,Shiro, Motoo,Ochiai, Masahito
supporting information; experimental part
p. 8931 - 8934
(2010/02/28)
Carbon-carbon coupling of C(sp3)-F bonds using alumenium catalysis
Dialkylalumenium cation equivalents coupled with the hexabromocarborane anion function as efficient and long-lived catalysts for alkylation of aliphatic C-F bonds (alkylative defluorination or AlkDF) by alkylaluminum compounds. Only C(sp3)-F bo
Gu, Weixing,Haneline, Mason R.,Douvris, Christos,Ozerov, Oleg V.
experimental part
p. 11203 - 11212
(2009/12/05)
More Articles about upstream products of 27415-42-5