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27848-81-3

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Preparation of (R)-(+)-Lithium Lactate
Optically pure (R)-(+)-lithium lactate (7) and its benzyl ether analogue (6a) were obtained from acetaldehyde using Eliel's 1,3-trans-oxathiane (1) as the chiral auxiliary for chromatographic separation.
Cervantes-Cuevas,Joseph-Nathan
p. 201 - 206
(2007/10/03)

Complete conversion of l-lactate into d-lactate. A generic approach involving enzymatic catalysis, electrochemical oxidation of NADH, and electrochemical reduction of pyruvate
L-Lactate was converted into D-lactate with a yield better than 97%, the system involving stereospecific catalysis of L-lactate oxidation by the rather cheap L-lactate dehydrogenase plus electrochemical regeneration of NAD+ at the anode and electrochemical reduction of pyruvate at the cathode. Such an approach can be extended to mere deracemization or complete inversion of all types of chiral α-alcohol-acids provided that the dehydrogenase related to the isomer to be inverted is available. Efficiency was not limited by enzyme or coenzyme deactivations.
Biade, Azz-Eddine,Bourdillon, Christian,Laval, Jean-Marc,Mairesse, Gilles,Moiroux, Jacques
p. 893 - 897
(2007/10/02)

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867-55-0
lithium L-lactate

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Chemical Properties

Appearance/Colour :white fine crystalline powder
Boiling Point: 227.6 °C at 760 mmHg
Flash Point:109.9 °C
Density: 1.09 g/mL at 25 °C(lit.)
Storage Temp.:2-8°C
Vapor Density: 1.03 (vs air)
Vapor Pressure: 52 mm Hg ( 37 °C)
Refractive Index: n20/D 1.377
BRN: 4823618
PSA: 60.36000
LogP: -1.88290

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