- Improved synthesis and crystal structure of the parent 1,3,5-trisilacyclohexane
-
The crystal structure and an improved synthesis of 1,3,5-trisilacyclohexane are reported. The solid state structure is compared with the reported structure determined in the gas phase by gas electron diffraction (GED). 1,3,5-Trisilacyclohexane adopts a chair conformation in the solid state. The Si-C bond lengths as well as all angles of 1,3,5-trisilacyclohexane in the solid state have similar dimensions compared to the structure in the gaseous phase.
- Weisheim, Eugen,Stammler, Hans-Georg,Mitzel, Norbert W.
-
-
Read Online
- PRODUCTION METHOD, SIC-BASED FILM-FORMING MATERIAL, AND SIC-BASED FILM
-
PROBLEM TO BE SOLVED: To provide a high-yielding method for producing trisilacyclohexane useful as a SiC-based film forming material. SOLUTION: A method for producing 1,3,5-trisilacyclohexane represented by the following formula comprises reducing an alkoxytrisilacyclohexane derivative represented by the following formula with a reductant such as LiAlH4. SELECTED DRAWING: None COPYRIGHT: (C)2017,JPOandINPIT
- -
-
Paragraph 0034-0035
(2017/05/18)
-