ELECTROCHEMICAL REDUCTION OF Fe(III), Cr(III), AND Mn(III) PORPHYRIN COMPLEXES IN DMSO
The half-wave potentials are given for the electrochemical reduction of Fe(III), Cr(III), and Mn(III) porphyrin complexes.Cyclic voltamperometry was used to study the reversibility of these reactions.An effect was demonstrated for the structure of the por
Klyuev, S. A.,Sheinin, V. B.,Berezin, B. D.,Tsyganov, D. V.,Vodzinskii, S. V.
Picosecond Absorption Studies on the Excited State of (μ-Oxo)bis
We have measured the kinetics and spectra of the intermediates of (μ-oxo)bis in various solvents.The spectra of the intermediate species were measured at various intervals of time from -100 to 4.3 ns after excitation with a 532- or 355-nm 25-ps pulse.The intermediate state, possibly a cation radical, was assigned to a monomer that forms the photodissociated pair TPPFeII+ + TPPFeIII-O- and yields a small amount of disproportionation reaction products, FeIITPP and TPPFeIV=O.t
Guest, C. R.,Straub, K. D.,Hutchinson, J. A.,Rentzepis, P. M.
p. 5276 - 5280
(2007/10/02)
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