The present invention relates to a method of reducing, cleaving and/or coupling at least one C=O, C-O, C=C or C=N bond of a compound, using a reagent comprising a stannyl cation.
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Page/Page column 16; 17
(2018/01/17)
cis- and trans-(4-alkylcyclohexyl)stannanes. Isomers for stereochemical studies of substitution at saturated carbon-tin bonds
The synthesis and characterization of pure cis- and trans-(4-methylcyclohexyl)- and cis- and trans-(4-tert-butylcyclohexyl)triphenylstannanes are described. Their conversion, by hydrochloric acid induced dephenylation-isopropylation, to the corresponding triisopropylstannanes proceeds smoothly to provide stereoisomers capable of providing significant information with respect to brominolysis and trifluoroacetolysis of the carbon-tin bond.
Olszowy, Henry A.,Kitching, William
p. 1670 - 1675
(2008/10/08)
Comparative toxicity of symmetric n-propylstannane and isopropylstannane.
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CAUJOLLE,LESBRE,MEYNIER,BLAIZOT
p. 1732 - 1734
(2007/11/03)
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