- Effect of ether on regioselectivity in hydrosilylation of 1,5-hexadiene with chlorohydrosilanes catalyzed by homogeneous platinum catalysts
-
Hydrosilylation of 1,5-hexadiene with chlorohydrosilanes catalyzed by homogeneous platinum catalyst to produce 5-hexenylchlorosilanes was studied. The presence of ether additives was highly effective in improving the regioselectivity and the yield. The formation of a double-bond rearrangement isomer, cis-, or trans-4-hexenylchlorosilanes, during the hydrosilylation was reduced drastically, as well. Copyright Taylor & Francis Group, LLC.
- Saiki, Takeaki
-
experimental part
p. 1556 - 1563
(2009/10/14)
-