Atom-bridged intermediates in N- and P-atom transfer reactions
Formal N-atom insertion into the metal metal triple bond of the diamagnetic compound 1, which has been known for over twenty years, results in the paramagnetic, nitridobridged molecule 2. The characterization of three such N- and P-atom bridged species is described, and their role as intermediates in three-electron atom transfer reactions is highlighted.
Johnson,Lee,Odom,Davis,Cummins
p. 87 - 91
(2008/10/09)
SYNTHESIS OF ALKYL ORTHOTITANATES IN TWO-PHASE SYSTEMS.
The authors have carried out an investigation aimed at development of more convenient methods for production of alkyl orthotitanates in two-phase systems. In studies of the reaction of titanium tetrachloride with alcohols in presence of organic amides the authors found that the latter are not indifferent solvents but take part in the reaction. The interaction of titanium tetrachloride, an organic amide, and an alcohol in 1:4:(8-9. 6) molar ratio results in splitting of the amide and formation of the corresponding amine hydrochloride and ester.
Yatluk,Suvorov
p. 1678 - 1680
(2008/10/08)
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