Cleavage of the C-Si bond in trifluoro(phenyl)silane with aliphatic alcohols
Trifluoro(phenyl)silane reacts with aliphatic alcohols under reflux. The reaction involves not only Si-F bond cleavage to form ethoxyfluoro(phenyl) silanes, but also C-Si bond cleavage to form benzene and alkoxyfluoro- and tetraalkoxysilanes. The formation of the latter products was proved by 19F and 29Si NMR spectroscopy and also by model disproportionation reactions of trifluoro(phenyl)silane with trimethoxy-(phenyl)-, tetramethoxy-, or tetraethoxysilanes.
Voronkov,Boyarkina,Gebel',Albanov,Basenko
p. 1927 - 1929
(2008/02/03)
ORGANOFLUOROSILYLAZINES
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Voronkov, M. G.,Basenko, S. V.,Gebel', I. A.,Vitkovskii, V. Yu.,Mirskov, R. G.