Total synthesis and stereochemical revision of (+)-aeruginosin 298-A.
[structure:see text] Novel routes toward both enantiomers of the bicyclic proline surrogate 2-carboxy-6-hydroxyoctahydroindole, i.e., Choi, were developed on the basis of the oxidative cyclization of L-tyrosine. Synthesis of the proposed sequence of (+)-a
Wipf,Methot
p. 4213 - 4216
(2007/10/03)
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