Cyclometalation of Phosphanes at Iridium(I): Interplay with Intramolecular Reductive Elimination Induced by the Strong π-Acceptor Ligands CO and NO+
Reaction of [{Ir(μ-Cl)(coe)2}2] (1; coe = cis-cyclooctene) with 4 equiv. of PtBu2Ph in CH2Cl2 at ambient temperature resulted in oxidative addition of one phosphane ligand affording the known cyclomet
B?ttcher, Hans-Christian,Junk, Merlin,Mayer, Peter,Beck, Wolfgang
Evidence for a strong similarity in conformational and phosphorus-31 NMR parameters between two series of trans-[(t-C4H9)2PX]2M(CO)Cl complexes [M = Rh(I), Ir(I); X = H, CH3, C2H5, n-C4H9, C6H5]
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Bushweller, C. Hackett,Rithner, Christopher D.,Butcher, David J.
p. 1967 - 1970
(2008/10/08)
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