cas 3279-27-4, 2-(1,1-DIMETHYLPROPYL)PHENOL | Articles data ｜lookchem

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3279-27-4

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Zirconia-modified superacid UDCaT-5: An efficient and versatile catalyst for alkylation reactions under solvent-free conditions
UDCaT-5, a modified version of zirconia, efficiently catalyzes alkylation of phenols with alcohols under environmentally safe, heterogeneous reaction conditions with high selectivity and in excellent yields. The high content present in UDCaT-5 with preservation of tetragonal phase of zirconia was responsible for the superactivity. Several phenolic compounds carrying either electron-sulfer releasing or electron-withdrawing substituents in the ortho, meta, and para positions afforded high yields of the products. Copyright Taylor & Francis Group, LLC.
Yadav, Ganapati D.,Pathre, Ganesh S.
p. 2684 - 2691
(2008/12/22)

EQULIBRATION OF TERT-ALKYLPHENOLS (THERMODYNAMIC ANALYSIS OF THE ALKYLATION OF PHENOLS USING BRANCHED-CHAIN OLEFINS).
The authors describe the results of a study to evaluate the thermodynamic properties of t-Alk PHI ; these results; combined with earlier results, have enabled the authors to complete a thermodynamic analysis of the process for preparing tertiary alkylphenols.
Nesterova,Verevkin,Malova,Pil'shchikov
p. 748 - 754
(2007/10/02)

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Chemical Properties

Appearance/Colour :clear liquid
Melting Point: -5oC BOLING
Boiling Point: 234.3 °C at 760 mmHg
Flash Point:111.2 °C
Density: 0.96 g/cm³
Vapor Pressure: 0.035mmHg at 25°C
Refractive Index: 1.509
PKA: 10.68±0.10(Predicted)
PSA: 20.23000
LogP: 3.07980

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