β-Trifluoroacetylvinyl phenyl sulfoxide - Synthesis, Diels-Alder reaction and computational study
The Diels-Alder reaction of sulfoxide 2 with 1,3-dienes in CH2Cl2 afforded the corresponding CF3-containing mono- and polycycloadducts. In the case of the reaction of sulfoxide 2 and sulfonium salt 10 with cyclopentadiene,
Krasovsky, Arkady L.,Pissarev, Serge A.,Nenajdenko, Valentine G.,Balenkova, Elizabeth S.
p. 2554 - 2560
(2007/10/03)
Diels-Alder reactions of β-trifluoroacetylvinylsulfones
Diels-Alder reactions of β-trifluoroacetylvinylsulfones with 1,3-dienes in CH2Cl2 afforded corresponding mono- and polycycloadducts. A possibility of stereo- and regioselective cycloaddition was investigated. Elimination of sulfonyl group from cycloadducts leads to α,β-unsaturated trifluoromethylketones in good yields.
Krasovsky, Arkady L,Nenajdenko, Valentine G,Balenkova, Elizabeth S
p. 201 - 209
(2007/10/03)
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