cas 334-28-1, 7-Fluoroheptanoic acid | Articles data ｜lookchem

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334-28-1

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Silver-catalyzed radical fluorination of alkylboronates in aqueous solution
We report herein an efficient and general method for the deboronofluorination of alkylboronates. Thus, with the catalysis of AgNO3, the reactions of various alkylboronic acids or their pinacol esters with Selectfluor reagent in acidic aqueous solution afforded the corresponding alkyl fluorides under mild conditions. A broad substrate scope and wide functional group compatibility were observed. A radical mechanism is proposed for this site-specific fluorination.
Li, Zhaodong,Wang, Zhentao,Zhu, Lin,Tan, Xinqiang,Li, Chaozhong
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p. 16439 - 16443
(2015/01/09)

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Chemical Properties

Melting Point: 10°C
Boiling Point: 242.9°Cat760mmHg
Flash Point:100.7°C
Density: 1.027g/cm³
Vapor Pressure: 0.0109mmHg at 25°C
Refractive Index: 1.4207
PSA: 37.30000
LogP: 1.99100

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