Electrogenerated superoxide anion induced oxidative amidation of benzoin
Amide function is very important in both organic and medicinal chemistry. Benzamides can be obtained in good to high yields by reaction of benzoin, primary or secondary amines, molecular oxygen and electrogenerated superoxide anion (obtained with galvanos
Pandolfi, Fabiana,Chiarotto, Isabella,Rocco, Daniele,Feroci, Marta
p. 358 - 367
(2017/10/06)
A more critical role for silicon in the catalytic Staudinger amidation: Silanes as non-innocent reductants
A revised pathway for the catalytic Staudinger amidation reaction is presented that involves the intervention of in situ-generated silyl esters as the species responsible for amidation.
Andrews, Keith G.,Denton, Ross M.
supporting information
p. 7982 - 7985
(2017/07/22)
Benzoic acid-catalyzed transamidation reactions of carboxamides, phthalimide, ureas and thioamide with amines
An efficient and simple method for the transamidation of carboxamides, phthalimide, ureas and thioamide with amines catalyzed by commercially available benzoic acid under metal-free conditions is described. Furthermore, to the best of our knowledge, this is the first report about the transamidation of an aromatic thioamide with amines.
Wu, Ji-Wei,Wu, Ya-Dong,Dai, Jian-Jun,Xu, Hua-Jian
supporting information
p. 2429 - 2436
(2014/09/30)
A NOVEL RETRO-ENE REACTION THE FRAGMENTATION OF N-BENZYL-2-BENZOYL-2-METHYLPROPANIMINE
N-benzyl-2-benzoyl-2-methylpropanimine treated with nucleophiles undergoes a fragmentation reaction that can be envisaged as a retro-ene reaction via the formation of an intermediate hemiketal.
Armesto, Diego,Ramos, Ana,Perez-Ossorio, Rafael
p. 5195 - 5198
(2007/10/02)
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