Perfluoroalkylation of simple inorganic molecules: A one step route to novel perfluoroalkylated compounds
Reactions of (CH3)3SiRf (Rf = CF3, C2F5) with NOCl, NO/NO2, SO2, CO2, in the presence of caesium fluoride provide a one step synthetic route to perfluoroalkylated compounds in very good yields.
Singh, Rajendra P.,Shreeve, Jean'ne M.
p. 1818 - 1819
(2007/10/03)
SYNTHESIS AND REACTIONS OF PENTAFLUOROETHANESULFINIC AND PENTAFLUOROETHANESULFONIC ACIDS
Pentafluoroethylmorpholinodifluorosulfurane was synthesized by the reaction of morpholinotrifluorosulfurane with tetrafluoroethylene in the presence of potassium fluoride and 18-crown-6.Hydrolysis of the products gave pentafluoroethanesulfinic acid, and oxidation gave pentafluoroethanesulfonic acid.The derivatives of these acids are described.
Radchenko, O. A,Il'chenko, A. Ya.,Yagupol'skii, L. M.
p. 421 - 425
(2007/10/02)
More Articles about upstream products of 344324-36-3